1234185-68-2Relevant articles and documents
The interplay of conformation and photophysical properties in deep-blue fluorescent oligomers
Li, Haiying,Batsanov, Andrei S.,Moss, Kathryn C.,Vaughan, Helen L.,Dias, Fernando B.,Kamtekar, Kiran T.,Bryce, Martin R.,Monkman, Andrew P.
supporting information; scheme or table, p. 4812 - 4814 (2010/08/20)
We report the synthesis, X-ray crystal structures and photophysics of new donor-acceptor oligomers of fluorene (F) and dibenzothiophene-S,S-dioxide (S) with constrained dihedral angles in the backbone. The materials display bright deep-blue fluorescence and evidence is presented for a planarised intramolecular charge-transfer (PICT) state in the F-S systems.