1234421-96-5

Basic information

• Product Name: 6-(t-butyl)-2-(diphenylphosphinoyloxy)-4-phenylaniline
• Synonyms: 6-(t-butyl)-2-(diphenylphosphinoyloxy)-4-phenylaniline
• CAS NO: 1234421-96-5
• Molecular Weight: 441.51
• Mol File: 1234421-96-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-(t-butyl)-2-(diphenylphosphinoyloxy)-4-phenylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(t-butyl)-2-(diphenylphosphinoyloxy)-4-phenylaniline(1234421-96-5)
• EPA Substance Registry System: 6-(t-butyl)-2-(diphenylphosphinoyloxy)-4-phenylaniline(1234421-96-5)

Safety Data

• Hazardous Substances Data: 1234421-96-5(Hazardous Substances Data)

Upstream product

• 70634-28-5 3-(tert-butyl)-4-nitrobiphenyl 
• 4559-70-0 Diphenylphosphine oxide 

Relevant articles and documents

Synthesis of o-(diphenylphosphinoyloxy)anilines by the rhodium-catalyzed reaction of nitroarenes and diphenylphosphine oxide

A rhodium complex Rh2(OAc)4 catalyzed the reaction of nitrobenzenes and diphenylphosphine oxide HP({double bond, long}O)Ph2 giving o-(diphenylphosphinoyloxy)anilines predominantly, which were accompanied by small amounts of the p-isomers. Nitorobenzenes possessing a bulky o-substituent, particularly o-(t-butyl)nitrobenzenes, underwent the reaction in high yields. The reaction is considered to involve the reductive formation of O-phosphinoyl-N-arylhydroxyamines from nitrobenzenes, and o-phosphinoyloxylation by the rearrangement.