123500-13-0

Basic information

• Product Name: N-(p-dimethylaminobenzylidene)-9-aminofluorene
• Synonyms: N-(p-dimethylaminobenzylidene)-9-aminofluorene
• CAS NO: 123500-13-0
• Molecular Weight: 312.414
• Mol File: 123500-13-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(p-dimethylaminobenzylidene)-9-aminofluorene(CAS DataBase Reference)
• NIST Chemistry Reference: N-(p-dimethylaminobenzylidene)-9-aminofluorene(123500-13-0)
• EPA Substance Registry System: N-(p-dimethylaminobenzylidene)-9-aminofluorene(123500-13-0)

Safety Data

• Hazardous Substances Data: 123500-13-0(Hazardous Substances Data)

Upstream product

• 525-03-1 9-aminofluorene 
• 100-10-7 4-dimethylamino-benzaldehyde 

Downstream Products

• 486-25-9 9-fluorenone 
• 123500-29-8 2,2-spiro(9',9'-fluorenyl)-4-(4'-dimethylaminophenyl)-7-phenyl-6,8-dioxo-3,7-diazabicyclo<3.3.0>octane 

Relevant articles and documents

Catalytic Asymmetric Umpolung Allylation of Imines

Here we report an iridium-catalyzed asymmetric umpolung allylation of imines as a general approach to prepare 1,4-disubstituted homoallylic amines, a fundamental class of compounds that are hitherto not straightforward to obtain. This transformation proceeds by a cascade involving an intermolecular regioselective allylation of 2-azaallyl anions and a following 2-aza-Cope rearrangement, utilizes easily available reagents and catalysts, tolerates a substantial scope of substrates, and readily leads to various enantioenriched, 1,4-disubstituted homoallylic primary amines.