123507-32-4Relevant articles and documents
Scandium trifluoromethanesulfonate-catalyzed chemoselective allylation reactions carbonyl compounds with tetraallylgermane in aqueous media
Akiyama, Takahiko,Iwai, Junko
, p. 853 - 856 (1997)
Scandium(III) triflate-catalyzed allylation of carbonyl compounds with tetraallylgermane proceeded readily in aqueous nitromethane to afford homoallyl alcohols in excellent to good yields. The presence of H2O is indispensable far the allylation of aldehydes to proceed smoothly. Aldehydes were allylated exclusively in the presence of ketone moieties.
Organic synthesis in solid media. Silica gel as an effective and reusable medium for the selective allylation of aldehydes with tetraallyltin
Jin, Yong Zhi,Yasuda, Noriyuki,Furuno, Hiroshi,Inanaga, Junji
, p. 8765 - 8768 (2003)
Wet silica gel promotes the chemoselective and almost complete allylation of aldehydes with 0.25-0.30 molar equivalents of tetraallyltin without an organic solvent, leaving no organotin compounds, requiring neither extraction nor chromatographic separatio
Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes
Tomifuji, Rei,Masuda, Shota,Kurahashi, Takuya,Matsubara, Seijiro
supporting information, p. 3834 - 3837 (2019/05/24)
Cationic cobalt porphyrin-catalyzed allylation of aldehydes with allyltrimethylsilanes is developed. The formation of the aldehyde-cobalt porphyrin complex, the key intermediate for the addition of allylsilanes, is confirmed by theoretical studies and syn
Ceric(IV) ammonium nitrate: A novel reagent for the synthesis of homoallyl alcohols
Yadav,Reddy,Krishna,Sadasiv,Chary, Ch. Janardhana
, p. 248 - 249 (2007/10/03)
A rapid and highly efficient method has been developed for the allylation of aldehydes with allyltributylstannane using a catalytic amount of eerie ammonium nitrate in acetonitrile under mild and neutral conditions to afford the corresponding homoallyl al