1235278-83-7

Basic information

• Product Name: [Mn₆O₂(Ph-sao)6(O₂P(Ph)2)2(MeOH)6]
• CAS NO: 1235278-83-7
• Molecular Weight: 2255.57
• Mol File: 1235278-83-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Mn₆O₂(Ph-sao)6(O₂P(Ph)2)2(MeOH)6](CAS DataBase Reference)
• NIST Chemistry Reference: [Mn₆O₂(Ph-sao)6(O₂P(Ph)2)2(MeOH)6](1235278-83-7)
• EPA Substance Registry System: [Mn₆O₂(Ph-sao)6(O₂P(Ph)2)2(MeOH)6](1235278-83-7)

Safety Data

• Hazardous Substances Data: 1235278-83-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 26094-08-6 2-hydroxybenzophenone oxime 
• 1707-03-5 diphenyl-phosphinic acid 

Relevant articles and documents

A new family of Mn6 SMMs using phosphinate ligands

A new family of hexametallic [MnIII6] Single-Molecule Magnets with general formula [Mn6O2(R-sao) 6(X)2(MeOH)4-6] (R = H, Me, Et or Ph; X = O2PHPh or O2P(Ph)2) have been synthesised and characterised. The molecules are new members of the [Mn6] family of SMMs in which the carboxylate ligands have been replaced with phenyl- and diphenylphosphinate. The magnetic cores remain largely unaltered meaning that structural distortions of the Mn-N-O-Mn torsion angles in the [Mn3O] subunits can be used to tune the magnetic properties, switching pairwise exchange interactions from antiferromagnetic to ferromagnetic. The results suggest that the Mn6 building block, be it ferro- or antiferromagnetically coupled, could be an important building block for the formation of novel, functional 0-3D materials. The Royal Society of Chemistry 2010.