123536-65-2

Basic information

• Product Name: (5S)-5-hydroxymethyl-2-cyclohexen-1-one
• Synonyms: (5S)-5-hydroxymethyl-2-cyclohexen-1-one
• CAS NO: 123536-65-2
• Molecular Weight: 126.155
• Mol File: 123536-65-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (5S)-5-hydroxymethyl-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (5S)-5-hydroxymethyl-2-cyclohexen-1-one(123536-65-2)
• EPA Substance Registry System: (5S)-5-hydroxymethyl-2-cyclohexen-1-one(123536-65-2)

Safety Data

• Hazardous Substances Data: 123536-65-2(Hazardous Substances Data)

Upstream product

• 1166841-87-7 acetic acid (S)-5-oxo-cyclohex-3-enylmethyl ester 
• 79644-03-4 (1S,5S)-6-oxabicyclo<3.2.1>oct-3-en-7-one 
• 123536-66-3 (1S,4S,5S)-4-iodo-6-oxabicyclo<3.2.1>octan-7-one 
• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 68295-80-7 (1S,5S)-5-Hydroxy-cyclohex-3-enecarboxylic acid methyl ester 
• 155751-19-2 (R)-5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 
• 123453-95-2 (1S,5S)-(-)-5-(hydroxymethyl)-2-cyclohexen-1-ol 
• 155703-00-7 Acetic acid (S)-3-methoxymethoxy-5-oxo-cyclohex-3-enylmethyl ester 
• 155702-97-9 5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 
• 19373-86-5 (+/-)-5-hydroxymethyl-3-methoxycyclohexenone 

Downstream Products

• 61228-92-0 (3S,8R,9R,10S)-(-)-periplanone-B 
• 123453-96-3 (5S,6S,1'R^*,2'R)-5-<(1-ethoxyethoxy)methyl>-6-(1'-hydroxy-3'-methyl-2'-phenylselenobutyl)-2-cyclohexen-1-one 
• 123453-96-3 (5S,6S)-5-(1-Ethoxy-ethoxymethyl)-6-((1S,2R)-1-hydroxy-3-methyl-2-phenylselanyl-butyl)-cyclohex-2-enone 
• 84162-00-5 (1S,5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-1-vinyl-2-cyclohexen-1-ol 

Relevant articles and documents

Synthesis and Evaluation of Oligomeric Thioether-Linked Carbacyclic β-(1?3)-Glucan Mimetics

Extrapolating from lessons learnt with previous low-molecular-weight β-(1?3)-glucan mimetics, we designed a series of minimal 2,4-dideoxy-thioether-linked carbacyclic β-(1?3)-glucan mimetics and synthesized di-, tri-, and tetramers in an enantiomerically

Chemo-enzymatic asymmetric total synthesis of penienone

An asymmetric synthesis of penienone has been accomplished from (R)-5-hydroxymethyl-2-cyclohexenone by adopting a linear strategy. Lipase-PS-catalyzed enzymatic kinetic resolution (EKR) and Julia-Kocienski olefination followed by substrate-directed anioni

Efficient synthesis of optically active cyclohexenones

Optically active 5-hydroxymethylcyclohexenones and 5- acetoxymethylcyclohexenones were efficiently obtained by enzymatic enantioselective esterification and chemical conversion.