1235889-83-4

Basic information

• Product Name: dimethyl 7-(4-methoxyphenyl)-6,7-dihydro-4bH-dibenzo[c,e]pyrrolo[1,2-a]azepine-5,5(9H)-dicarboxylate
• CAS NO: 1235889-83-4
• Molecular Weight: 457.526
• Mol File: 1235889-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl 7-(4-methoxyphenyl)-6,7-dihydro-4bH-dibenzo[c,e]pyrrolo[1,2-a]azepine-5,5(9H)-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 7-(4-methoxyphenyl)-6,7-dihydro-4bH-dibenzo[c,e]pyrrolo[1,2-a]azepine-5,5(9H)-dicarboxylate(1235889-83-4)
• EPA Substance Registry System: dimethyl 7-(4-methoxyphenyl)-6,7-dihydro-4bH-dibenzo[c,e]pyrrolo[1,2-a]azepine-5,5(9H)-dicarboxylate(1235889-83-4)

Safety Data

• Hazardous Substances Data: 1235889-83-4(Hazardous Substances Data)

Upstream product

• 316-31-4 5H-dibenzazepine 
• 75073-97-1 dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate 

Downstream Products

• 1235889-90-3 dimethyl 7-(4-methoxyphenyl)-6,7-dihydro-4bH-dibenzo[c,e]pyrrolo[1,2-a]azepine-5,5(9H)-dicarboxylate trifluoroacetate 

Relevant articles and documents

Dynamic kinetic asymmetric synthesis of substituted pyrrolidines from racemic cyclopropanes and aldimines: Reaction development and mechanistic insights

An enantioselective preparation of 2,5-cis-disubstituted pyrrolidines has been achieved via a dynamic kinetic asymmetric transformation (DyKAT) of racemic donor-acceptor cyclopropanes and (E)-aldimines. Mechanistic studies suggest that isomerization of the aldimine or resultant iminium to the Z geometry is not a pathway that furnishes the observed 2,5-cis-disubstituted products.