123623-95-0

Basic information

• Product Name: (C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2⁽²⁺⁾*2BF₄^(1-)=(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2(BF₄)2
• CAS NO: 123623-95-0
• Molecular Weight: 948.398
• Mol File: 123623-95-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2⁽²⁺⁾*2BF₄^(1-)=(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2(BF₄)2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2⁽²⁺⁾*2BF₄^(1-)=(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2(BF₄)2(123623-95-0)
• EPA Substance Registry System: (C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2⁽²⁺⁾*2BF₄^(1-)=(C₁₂H₈N₂)2Fe{CNC(CH₃)2(CHCH₂CH₂CH(CH₃)CH₂C(O))}2(BF₄)2(123623-95-0)

Safety Data

• Hazardous Substances Data: 123623-95-0(Hazardous Substances Data)

Upstream product

• 15362-08-0 dicyano-bis-(1,10-phenanthroline)-iron(II) dihydrate 
• 89-82-7 pulegone 

Relevant articles and documents

γ-Oxoisocyanid-Komplexe von Eisen(II), Ruthenium(II), Palladium(II) und Platin(II) aus Cyano-Komplexen und α,β-ungesaettigten Carbonylverbindungen in Gegenwart von Et2O-HBF4. Kristallstrukturanalyse von cis-(phen)2Fe22+(BF4-)2

Pseudohalogeno Metal Compounds, LXXIII. - γ-Oxoisocyanide Complexes of Iron(II), Ruthenium(II), Palladium(II), and Platinum(II) from Cyano Complexes and α,β-Unsaturated Carbonyl Compounds in the Presence of Et2O-HBF4.Crystal Structure of cis-(phen)2Fe22+(BF4-)2 Reactions of trans-(R3P)2M(CN)2 (M=Pd, Pt), cis-, Cp(dppe)Fe(CN), and Cp(Ph3P)2Ru(CN) with several α,β-unsaturated ketones in the presence of Et2O-HBF4 yield complexes containing the γ-oxoisocyanide ligand: trans-1R2-CHR3-C(O)R4)2>2+(BF4-)2 (5-8), trans-1R2-CHR3-C(O)R4)>+ BF4- (9), cis-1R2-CHR3-C(O)R4)2>2+(BF4-)2 (10), and 1R2-CHR3-C(O)R4)>+ BF4- (11,12) (M=Fe, Ru; L = PPh3, 0.5 dppe).The compounds were characterized by their spectroscopic data, 10g by X-ray crystallography.The carbonyl function of the coordinated ligands could be reduced by NaBH4/CeCl3*6H2O in some cases to give complexes of γ-hydroxyisocyanide and oxazine-2-ylidene ligands.