123640-93-7 Usage
Description
4,4'-Bis(triethoxysilyl)-1,1'-biphenyl (BTESB) is an organic compound that possesses unique properties due to its molecular structure, which includes a biphenyl core with two triethoxysilyl groups attached to the 4,4' positions. 4 4'-BIS(TRIETHOXYSILYL)-1 1'-BIPHENYL is known for its potential applications in various fields, particularly in the synthesis of advanced materials and as an indicator for chirality.
Uses
Used in Chemical Synthesis:
4,4'-Bis(triethoxysilyl)-1,1'-biphenyl is used as a precursor for the synthesis of various advanced materials, such as helical silica nanotubes and nanoribbons, biphenyl-bridged alkoxysilane-based crosslinked polyalkoxysilanes, and biphenylene-bridged silsesquioxane thin films. The compound's unique structure allows for the creation of materials with specific properties and applications.
Used in Material Science:
In the Material Science industry, 4,4'-Bis(triethoxysilyl)-1,1'-biphenyl is used as a precursor for the development of novel materials with enhanced properties. These materials can be utilized in various applications, such as coatings, adhesives, and composites, due to their improved mechanical, thermal, and chemical resistance.
Used in Nanotechnology:
4,4'-Bis(triethoxysilyl)-1,1'-biphenyl is used as a precursor in the synthesis of helical 4,4'-biphenylene-silica nanotubes and nanoribbons. These nanostructures have potential applications in fields such as electronics, sensors, and drug delivery systems, due to their unique properties and high surface area.
Used in Analytical Chemistry:
In the Analytical Chemistry industry, 4,4'-Bis(triethoxysilyl)-1,1'-biphenyl is used as an indicator to determine the chirality of helical silica nanotubes. The compound's ability to interact with these nanostructures allows for the assessment of their structural properties, which is crucial for their potential applications in various fields.
Used in Sol-Gel Processing:
4,4'-Bis(triethoxysilyl)-1,1'-biphenyl is used as a precursor in the sol-gel method to produce biphenylene-bridged silsesquioxane thin films. These films have potential applications in the development of optical devices, sensors, and protective coatings due to their unique optical and mechanical properties.
Check Digit Verification of cas no
The CAS Registry Mumber 123640-93-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,6,4 and 0 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 123640-93:
(8*1)+(7*2)+(6*3)+(5*6)+(4*4)+(3*0)+(2*9)+(1*3)=107
107 % 10 = 7
So 123640-93-7 is a valid CAS Registry Number.
123640-93-7Relevant articles and documents
Synthesis of new microporous layered organic-inorganic hybrid nanocomposites by alkoxysilylation of a crystalline layered silicate, ilerite
Ishii, Ryo,Ikeda, Takuji,Itoh, Tetsuji,Ebina, Takeo,Yokoyama, Toshirou,Hanaoka, Takaaki,Mizukami, Fujio
, p. 4035 - 4043 (2006)
We have developed microporous organic-inorganic hybrid nanocomposites by alkoxysilylation of 4,4′-biphenyl-bridged alkoxysilane compounds, which contain triethoxysilyl, methyldiethoxysilyl, and dimethylethoxysilyl groups at each end of the 4,4′-biphenylene unit ((CH3)n(C 2H5O)3-n-Si-C12H8-Si- (OC2H5)3-n(CH3)n, n = 0, 1, or 2, abbreviated as BESB(0), BESB(2), or BESB(4), respectively, where the number in parentheses indicates the number of methyl groups in these molecules), in the interlayer of a crystalline layered silicate, ilerite. XRD, 29Si solid-state NMR and fluorescence spectroscopy revealed the immobilization and bridging formation of the BESB molecules between the silicate layers by condensation, not only with H-ilerite, but also with the BESB molecules. The interlayer structures exhibited different molecular arrangements. BESB(0) and BESB(4) molecules are present as a monolayer arrangement in which BESB(0) molecules form the oligomeric species caused by close stacking like a dimer. BESB(2) molecules form mainly bilayer-like aggregates in the interlayer. The structural differences are caused by the different reactivities of the BESB molecules, which control their polymerization in the interlayer. The resultant BESB(0)- and BESB(2)-ilerite had high microporosity with BET surface areas (508 and 578 m2 g-1 for BESB(0)- and BESB(2)-ilerite, respectively). The micropores showed higher toluene adsorptivity than several other porous silica materials due to the successful surface modification. Consequently, this approach provides a new method for constructing novel microporous nanocomposites, the key to improved selectivity and activity in separation and catalytic applications. The Royal Society of Chemistry 2006.
