1237588-13-4 Usage
General Description
2-(Di-1-adamantylphosphino)phenylpiperidine is a chemical compound with the molecular formula C28H38NP. It is a phosphine ligand commonly used in organic and inorganic chemistry as a catalyst for various chemical reactions. The compound is structurally derived from piperidine and is characterized by the presence of a phosphino group and an adamantyl group. Its unique structure and properties make it useful for a wide range of applications in chemical synthesis, including asymmetric hydrogenation, C-C bond formation, and other important reactions in organic chemistry. Furthermore, its rigid and bulky structure makes it an effective chiral ligand for asymmetric catalysis.
Check Digit Verification of cas no
The CAS Registry Mumber 1237588-13-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,3,7,5,8 and 8 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1237588-13:
(9*1)+(8*2)+(7*3)+(6*7)+(5*5)+(4*8)+(3*8)+(2*1)+(1*3)=174
174 % 10 = 4
So 1237588-13-4 is a valid CAS Registry Number.
1237588-13-4Relevant articles and documents
A P,N-Ligand for palladium-catalyzed ammonia arylation: Coupling of deactivated aryl chlorides, chemoselective arylations, and room temperature reactions
Lundgren, Rylan J.,Peters, Brendan D.,Alsabeh, Pamela G.,Stradiotto, Mark
supporting information; experimental part, p. 4071 - 4074 (2010/07/05)
(Figure Presented) Amazing ammonia: A new air-stable P,N-ligand (Mor-DalPhos) is reported that enables the palladium-catalyzed crosscoupling of ammonia to a variety of aryl chloride and aryl tosylate substrates with high chemoselectivity and, for the first time, at room temperature (see scheme; Ad = adamantyl, Ts=para-toluenesulfonyl).
