123808-27-5Relevant articles and documents
THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM APHIDICOLA
Hanson, James R.,Hitchcock, Peter B.,Manickavasagar, Revathy
, p. 1023 - 1026 (1994)
Globulol and 7-epiglobulol were shown to be hydroxylated by Cephalosporium aphidicola on one (C-14) of the methyl groups geminal to the cyclopropane ring in 48.5 and 56percent yield, respectively.The significance of this hydroxylation adjacent to a cyclopropane ring is noted. - Key words: Cephalosporium aphidicola; globulol; 7-epiglobulol; sesquiterpenoid; microbiological hydroxylation.