123974-18-5Relevant articles and documents
A convenient method for the synthesis of β,γ-unsaturated amines from alkenes via α,β-unsaturated diphenylsulfonium salts
Yamanaka, Hiroyuki,Matsuo, Jun-Ichi,Kawana, Asahi,Mukaiyama, Teruaki
, p. 626 - 627 (2003)
1,1-Disubstituted and trisubstituted alkenes were converted into the corresponding β,γ-unsaturated amines 4 via three steps: the initial formation of α,β-unsaturated diphenylsulfonium triflates 2 from alkenes and diphenyl(trifluoromethanesulfonyloxy)sulfo
Anti-Markovnikov rearrangement in sulfur mediated allylic C-H amination of olefins
Zhang, Zhong,Du, Hongguang,Xu, Jiaxi,Li, Pingfan
supporting information, p. 11547 - 11550 (2016/10/03)
Cationic rearrangement reactions usually follow Markovnikov's rule to give more substituted carbocations as stable intermediates. During our study on sulfur mediated allylic C-H amination of olefins, very rare cases of anti-Markovnikov rearrangement from secondary carbocations toward primary carbocations or primary triflates were observed.
SYNTHESIS OF DERIVATIVES OF 3-HYDROXYMETHYL-3-PHENYLAZETIDINE AND ATTEMPTED CONVERSIONS TO 3-PHENYL-1-AZABICYCLOPENTANE OR 3-PHENYL-1-AZABICYCLOHEXANE
Anderson, Arthur G.,Jewell, Richard A.
, p. 81 - 86 (2007/10/02)
The synthesis of eleven new derivatives of 3-hydroxymethyl-3-phenylazetidine and attempts to form the corresponding 1-azabicyclopentane or 1-azabicyclostructure from these are described.
