124017-59-0Relevant articles and documents
Stereospecific conrotatory ring opening of a tetraaryl thiirane cation radical
Glass, Richard S.,Jung, Woncheol
, p. 1137 - 1138 (1994)
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THIONES AS SUPERDIPOLAROPHILES
Huisgen, Rolf,Langhals, Elke
, p. 5369 - 5372 (2007/10/02)
According to kinetic measurements,the 1,3-cycloadditions of diphenyl-diazomethane to thioketones are much faster than those to α,β-unsaturated carbonyl compounds and nitriles previously regarded as record dipolarophiles.The primary cycloadducts are tetrasubstituted 1,3,4-thiadiazolines which extrude N2 and furnish thiiranes via thiocarbonyl ylides.