124081-36-3Relevant articles and documents
Novel Method for the Preparation of Triethylsilyl Peroxides from Olefins by the Reaction with Molecular Oxygen and Triethylsilane Catalyzed by Bis(1,3-diketonato)cobalt(II)
Isayama, Shigeru,Mukaiyama, Teruaki
, p. 573 - 576 (2007/10/02)
In the presence of a catalytic amount of bis(1,3-diketonato)cobalt(II), various olefins react with molecular oxygen and triethylsilane at room temperature to give the corresponding triethylsilyl peroxides in high yields under neutral conditions.The reaction provides a new method for the preparation of various peroxides directly from olefins.