1241784-90-6

Basic information

• Product Name: C₂₂H₃₁⁽²⁾HN₂O₅SSi
• CAS NO: 1241784-90-6
• Molecular Weight: 465.65
• Mol File: 1241784-90-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₁⁽²⁾HN₂O₅SSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₁⁽²⁾HN₂O₅SSi(1241784-90-6)
• EPA Substance Registry System: C₂₂H₃₁⁽²⁾HN₂O₅SSi(1241784-90-6)

Safety Data

• Hazardous Substances Data: 1241784-90-6(Hazardous Substances Data)

Upstream product

• 1241784-88-2 C₂₂H₃₀N₂O₅SSi 

Relevant articles and documents

Self-sacrificing acetylation observed during attempted desilylation of 1-[4-benzenesulfonyl-3-O-(tert-butyldimethylsilyl)-2-deoxy-5-O-methanesulfonyl- α-l-threo-pentofuranosyl]thymine

Desilylation of 1-[4-benzenesulfonyl-3-O-(tert-butyldimethylsilyl)-2-deoxy- 5-O-methanesulfonyl-α-l-threo-pentofuranosyl]thymine (4) with Bu 4NF/THF, when carried out at room temperature, gave four products. Among these, there were 1-[3-O-acetyl-4-benzenesulfonyl-2-deoxy-5-O- methanesulfonyl-α-l-threo-pentofuranosyl]thymine (7) and thymine. A possible reaction mechanism is proposed, which suggests the origin of 3′-O-acetyl group of 7 and thymine as well as structures of the other two products (9a and 9b).