1241904-56-2

Basic information

• Product Name: (η⁵-C₅H₄PPh₂)Re(CO)₂P(OMe)₃
• CAS NO: 1241904-56-2
• Molecular Weight: 615.576
• Mol File: 1241904-56-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η⁵-C₅H₄PPh₂)Re(CO)₂P(OMe)₃(CAS DataBase Reference)
• NIST Chemistry Reference: (η⁵-C₅H₄PPh₂)Re(CO)₂P(OMe)₃(1241904-56-2)
• EPA Substance Registry System: (η⁵-C₅H₄PPh₂)Re(CO)₂P(OMe)₃(1241904-56-2)

Safety Data

• Hazardous Substances Data: 1241904-56-2(Hazardous Substances Data)

Upstream product

• 121-45-9 phosphorous acid trimethyl ester 

Relevant articles and documents

Heterobimetallic RePd complexes bridged by η1: η5-Ph2PC5H4 ligand. Synthesis, electronic and crystal structure of (CO)2(PR3) (η5-C5H4PPh2)Re-PdCl 2, R = Me and OMe

The new rhenium complexes (η5-C5H 4PPh2)Re(CO)2(PR3) (R = Me (1) and OMe (2)) were prepared photochemically from (η5-C 5H4PPh2)Re(CO)3 in the presence of PMe3 or P(OMe)3. Further reaction of these ligands with PdCl2(NCPh)2 in chloroform, produces the heterobimetallic complexes (CO)2(PMe3)(η5-C 5H4PPh2)Re-PdCl2 (3) and (CO) 2(P(OMe)3)(η5-C5H 4PPh2)Re-PdCl2 (4). IR spectroscopy reveals that both complexes possess a Re-Pd interaction which was confirmed by X-ray crystallography (Re-Pd bond distance = 2.762 A in 3 and 2.774 A in 4). Relativistic functional density theory calculations have also been carried out in order to probe the bonding in these compounds.