124272-67-9

Basic information

• Product Name: Pt₂Cl(ONO₂)((C₆H₅)2PCH₂P(C₆H₅)2)2
• CAS NO: 124272-67-9
• Molecular Weight: 1256.41
• Mol File: 124272-67-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt₂Cl(ONO₂)((C₆H₅)2PCH₂P(C₆H₅)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pt₂Cl(ONO₂)((C₆H₅)2PCH₂P(C₆H₅)2)2(124272-67-9)
• EPA Substance Registry System: Pt₂Cl(ONO₂)((C₆H₅)2PCH₂P(C₆H₅)2)2(124272-67-9)

Safety Data

• Hazardous Substances Data: 124272-67-9(Hazardous Substances Data)

Upstream product

• 18024-34-5 1,2-bis(diphenylphosphino)ethane digold(I) dichloride 
• 61250-65-5 dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) 
• 37095-27-5 (bis(diphenylphosphino)methane)bis(chlorogold(I)) 

Relevant articles and documents

A route to trinuclear platinum-gold clusters

New A-frame cluster complexes have been prepared by addition of electrophilic gold fragments to the Pt-Pt bond of , dppm = Ph2PCH2PPh2.For example, gave and gave NO3.The complexes reacted with to give BF4 when n = 1 or 2, but the bridged bis(A-frame) cluster complex 2CH2>(BF4)2 when n = 3.In contrast, CuCl reacted with to give .Attempts to synthesize A-frame clusters containing Pt2Ag, Pt2Cu, Pd2Au, or PdPtAu units were unsuccessful, and it is concluded that these units are considerably weaker than the analogous 3-center 2-electron bond of the Pt2Au unit.The AuCl unit is displaced from on reaction with diazomethane, with formation of .Key words: platinum, gold, cluster, copper, silver.