1246451-95-5

Basic information

• Product Name: 6-N-(4'-nitrobenzylidene)aminodeoxyvasicinone
• Synonyms: 6-N-(4'-nitrobenzylidene)aminodeoxyvasicinone
• CAS NO: 1246451-95-5
• Molecular Weight: 334.334
• Mol File: 1246451-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-N-(4'-nitrobenzylidene)aminodeoxyvasicinone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-N-(4'-nitrobenzylidene)aminodeoxyvasicinone(1246451-95-5)
• EPA Substance Registry System: 6-N-(4'-nitrobenzylidene)aminodeoxyvasicinone(1246451-95-5)

Safety Data

• Hazardous Substances Data: 1246451-95-5(Hazardous Substances Data)

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 55727-53-2 7-amino-2,3-dihydropyrrolo[2,1-b]quinazolin-9(1H)-one 

Downstream Products

• 555-16-8 4-nitrobenzaldehdye 
• 55727-53-2 7-amino-2,3-dihydropyrrolo[2,1-b]quinazolin-9(1H)-one 

Relevant articles and documents

Directions of reactions of 6-amino-, -acetylamino-, and- benzoylaminodeoxyvasicinones with aldehydes

6-Acetylamino- and -benzoylamino-9-arylidenedeoxyvasicinones were synthesized by reaction of 6-amino-(3), -acetylamino- (4), and -benzoylamino- (5) -deoxyvasicinones (DOV) with aromatic aldehydes and furfurol in glacial acetic acid. It was shown that the amino group of 6-aminodeoxyvasicinone underwent acylation upon reaction with aldehydes to form 6-acetylamino-DOV, which reacted with aldehydes to form 9-arylidene derivatives. Carrying out this condensation in toluene, o-xylene, and ethanol produced a mixture of condensation products at the 6-amino- and α-CH2-groups. It was found that condensati on of 3 with 4-nitrobenzaldehyde in pyridine formed exclusively the Schiff bases. Methods for preparing 6-nitrodeoxyvasicinone and for its reduction were improved.