1246668-97-2Relevant articles and documents
Dehydrogenative functionalization of C(sp3)-H bonds adjacent to a heteroatom mediated by oxoammonium salts
Richter, Heinrich,Mancheno, Olga Garcia
experimental part, p. 4460 - 4467 (2010/10/04)
The first oxoammonium salt mediated formation of C-C bonds from, benzylic C(sp3)-H bonds adjacent to an oxygen or nitrogen, atom by dehydrogenative coupling with enolizable carbonyls has been developed. The use of these oxi- dants in combination with catalytic amounts of Fe(OTf)2 as Lewis acid, allows the reaction to be carried out under mild conditions, leading to the corresponding coupling products in moderate to good yields.
