124668-67-3

Basic information

• Product Name: O-(methoxycarbonylmethyl)-N-phenylcarbamate
• Synonyms: O-(methoxycarbonylmethyl)-N-phenylcarbamate
• CAS NO: 124668-67-3
• Molecular Weight: 209.202
• Mol File: 124668-67-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-(methoxycarbonylmethyl)-N-phenylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: O-(methoxycarbonylmethyl)-N-phenylcarbamate(124668-67-3)
• EPA Substance Registry System: O-(methoxycarbonylmethyl)-N-phenylcarbamate(124668-67-3)

Safety Data

• Hazardous Substances Data: 124668-67-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 4264-00-0 O-(phenylcarbamoyl)glycolic acid 
• 96-35-5 glycolic acid methyl ester 
• 103-71-9 phenyl isocyanate 
• 861523-30-0 methoxycarbonyloxy-acetic acid anilide 

Relevant articles and documents

KINETICS AND MECHANISM OF REVERSIBLE, BASE-CATALYSED RING CLOSURE OF 3-(METHOXYCARBONYL)PROPIONANILIDE AND O-(METHOXYCARBONYLMETHYL)-N-PHENYLCARBAMATE

The rate constants of reversible, base-catalysed ring closure of 3-(methoxycarbonyl)propionanilide (I) and O-(methoxycarbonylmethyl)-N-phenylcarbamate (II) to 1-phenyl-2,5-pyrrolidinedione (III) and 3-phenyl-2,4-oxazolidinedione (IV), respectively, and the rates of solvolyses of the cyclization products III and IV in water and methanol have been measured.In both cases, an equilibrium is established between the starting ester and the cyclization product in methoxide solutions which is strongly shifted in favour of the starting ester.In the case of ester II in methoxidesolutions, the cyclization is followed by a much slower splitting of the cyclization product to give glycolic acid anilide.The effects of the group X=NH, CH2, O, S in the esters RNHCOXCH2COOCH3 on the rates of the cyclization and solvolysis of the cyclization products is discussed.