1246937-26-7

Basic information

• Product Name: S(CH₂S)2Pt(dppe)
• CAS NO: 1246937-26-7
• Molecular Weight: 717.756
• Mol File: 1246937-26-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S(CH₂S)2Pt(dppe)(CAS DataBase Reference)
• NIST Chemistry Reference: S(CH₂S)2Pt(dppe)(1246937-26-7)
• EPA Substance Registry System: S(CH₂S)2Pt(dppe)(1246937-26-7)

Safety Data

• Hazardous Substances Data: 1246937-26-7(Hazardous Substances Data)

Upstream product

• 289-16-7 1,2,4-trithiolane 
• 83571-74-8 (Ph2PCH2CH2PPh2)Pt(η-C2H4) 

Relevant articles and documents

Reactions of 1,2,4-Trithiolane and its 4-S-Oxide with diphosphane Pt 0 complexes

Reactions of 1,2,4-trithiolanes with Pt0 complexes often proceed via an oxidative addition of the Pt0 complex fragment into the S-S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six-membered intermediate 5a, formed in the course of the reaction of the parent 1,2,4-trithiolane (1a) and Pt0 complex 4, was detected by means of low-temperature NMR spectroscopy. Stable derivatives of this type (compounds 9, 11 and 12) were isolated either by using (dppe)Pt0 complex 8 or 1,2,4-trithiolane 4-Soxide (10). The molecular structures of platinum complexes 9, 11 and 12, as well as their unexpected stability, are discussed.