124870-40-2

Basic information

• Product Name: 2-{2-[Dimethyl-(4-trifluoromethyl-phenyl)-silanyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol
• CAS NO: 124870-40-2
• Molecular Weight: 446.388
• Mol File: 124870-40-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-{2-[Dimethyl-(4-trifluoromethyl-phenyl)-silanyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{2-[Dimethyl-(4-trifluoromethyl-phenyl)-silanyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol(124870-40-2)
• EPA Substance Registry System: 2-{2-[Dimethyl-(4-trifluoromethyl-phenyl)-silanyl]-phenyl}-1,1,1,3,3,3-hexafluoro-propan-2-ol(124870-40-2)

Safety Data

• Hazardous Substances Data: 124870-40-2(Hazardous Substances Data)

Upstream product

• 2786-01-8 (4-trifluoromethylphenyl)lithium 
• 124870-36-6 1,1-Dimethyl-3,3-bis-trifluoromethyl-1,3-dihydro-benzo[c][1,2]oxasilole 

Downstream Products

• 124870-36-6 1,1-Dimethyl-3,3-bis-trifluoromethyl-1,3-dihydro-benzo[c][1,2]oxasilole 
• 124870-37-7 1-Methyl-3,3-bis-trifluoromethyl-1-(4-trifluoromethyl-phenyl)-1,3-dihydro-benzo[c][1,2]oxasilole 

Relevant articles and documents

INTRAMOLECULAR CYCLIZATION OF o-SILYLBENZYL ALCOHOLS WITH ELIMINATION OF HYDROCARBON VIA HYPERVALENT SILICON INTERMEDIATES: EFFECT OF STRUCTURE ON THE SELECTIVITY FOR ELIMINATION

o-Silylbenzyl alcohols (1a-1e) cyclized with elimination of hydrocarbon to give cyclic silanes (2) in quantitative yield.The cyclization took place only in aprotic polar solvents such as acetonitrile, indicating that the intermediate of the cyclization wa