124944-40-7

Basic information

• Product Name: 1′-(diphenylphosphino)ferrocene-1-carbaldehyde
• Synonyms: 1′-(diphenylphosphino)ferrocene-1-carbaldehyde
• CAS NO: 124944-40-7
• Molecular Weight: 398.224
• Mol File: 124944-40-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1′-(diphenylphosphino)ferrocene-1-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 1′-(diphenylphosphino)ferrocene-1-carbaldehyde(124944-40-7)
• EPA Substance Registry System: 1′-(diphenylphosphino)ferrocene-1-carbaldehyde(124944-40-7)

Safety Data

• Hazardous Substances Data: 124944-40-7(Hazardous Substances Data)

Upstream product

• 12093-10-6 ferrocenecarboxaldehyde 
• 1079-66-9 chloro-diphenylphosphine 
• 124944-39-4 1-(tri-n-butylstannyl)-1'-(diphenylphosphino)ferrocene 
• 68-12-2 N,N-dimethyl-formamide 
• 185223-97-6 1′-(diphenylphosphino)-1-bromoferrocene 

Downstream Products

• 1246383-83-4 (PPh₂C₅H₄)Fe(C₅H₄CHCHCOC₅H₄N) 
• 1423762-44-0 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1) 
• 1423762-51-9 C₂₃H₂₄BFeP 
• 904690-32-0 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde 
• 386702-89-2 1′-(diphenylphosphino)ferrocene-1-carbaldehyde 
• 1513853-47-8 1'-(diphenylphosphino)ferrocene-1-carboxaldehyde oxime 

Relevant articles and documents

Chiral sulfinamide monophosphine ligand based on ferrocene skeleton and preparation method for full configurations of chiral sulfinamide monophosphine ligand

The invention belongs to the technical field of organic chemistry, and particularly relates to a chiral sulfinamide monophosphine ligand based on a ferrocene skeleton and a preparation method for fullconfigurations of the chiral sulfinamide monophosphine ligand. Four optically pure chiral monophosphine ligands 1(S, R), 1 (R, R), 1 (S, S) and 1 (R, S) are obtained by using chiral sulfinyl imide with two configurations including R and S through two ways including a step-by-step method and a one-pot method. The synthesized sulfonamide chiral monophosphine ligand (denoted as HK-Phos) based on the ferrocene skeleton shows certain reaction activity and stereoselectivity as a chiral ligand in the research of asymmetric synthesis catalyzed by transition metal, and has potentialand wide application value.

1,1′-Bis(tri-n-butylstannyl)ferrocene: Selective transmetalation applied to the synthesis of new ferrocenyl ligands

Selective transmetalation of one tri-n-butylstannyl group of [η5-(Bu3Sn)C5H4]2Fe (1) with 1 molar equiv of n-BuLi, followed by treatment with Ph2PCl or N,N-dimethylformamide, produced 1-(tr