1250258-94-6Relevant articles and documents
Trapping of Difluorocarbene by Frustrated Lewis Pairs
Dilman, Alexander D.,Korlyukov, Alexander A.,Smirnov, Vladimir O.,Volodin, Alexander D.
, (2020)
Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho-position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
Rhodium-Catalyzed PIII-Directed ortho-C?H Borylation of Arylphosphines
Wen, Jian,Wang, Dingyi,Qian, Jiasheng,Wang, Di,Zhu, Chendan,Zhao, Yue,Shi, Zhuangzhi
, p. 2078 - 2082 (2019/02/01)
Transition-metal-mediated metalation of an aromatic C?H bond that is adjacent to a tertiary phosphine group in arylphosphines via a four-membered chelate ring was first discovered in 1968. Herein, we overcome a long-standing problem with the ortho-C?H activation of arylphosphines in a catalytic fashion. In particular, we developed a rhodium-catalyzed ortho-selective C?H borylation of various commercially available arylphosphines with B2pin2 through PIII-chelation-assisted C?H activation. This discovery is suggestive of a generic platform that could enable the late-stage modification of readily accessible arylphosphines.
Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine-Borane Catalysts: On the Role of the Formaldehyde Adduct
Declercq, Richard,Bouhadir, Ghenwa,Bourissou, Didier,Légaré, Marc-André,Courtemanche, Marc-André,Nahi, Karine Syrine,Bouchard, Nicolas,Fontaine, Frédéric-Georges,Maron, Laurent
, p. 2513 - 2520 (2015/04/22)
Ambiphilic phosphine-borane derivatives 1-B(OR)2-2-PR′2-C6H4 (R′ = Ph (1), iPr (2); (OR)2 = (OMe)2 (1a, 2a); catechol (1b, 2b) pinacol (1c, 2c), -OCH2C-(CH3)2CH2O- (1d)) were tested as catalysts for the hydroboration of CO2 using HBcat or BH3·SMe2 to generate methoxyboranes. It was shown that the most active species were the catechol derivatives 1b and 2b. In the presence of HBcat, without CO2, ambiphilic species 1a, 1c, and 1d were shown to transform to 1b, whereas 2a and 2c were shown to transform to 2b. The formaldehyde adducts 1b·CH2O and 2b·CH2O are postulated to be the active catalysts in the reduction of CO2 rather than being simple resting states. Isotope labeling experiments and density functional theory (DFT) studies show that once the formaldehyde adduct is generated, the CH2O moiety remains on the ambiphilic system through catalysis. Species 2b·CH2O was shown to exhibit turnover frequencies for the CO2 reduction using BH3·SMe2 up to 228 h-1 at ambient temperature and up to 873 h-1 at 70 °C, mirroring the catalytic activity of 1b. (Figure Presented)