125065-60-3

Basic information

• Product Name: Acetic acid, [(2-phenylethenyl)thio]-, ethyl ester, (Z)-
• CAS NO: 125065-60-3
• Molecular Formula: C12H14O2S
• Molecular Weight: 222.308
• Mol File: 125065-60-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(2-phenylethenyl)thio]-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(2-phenylethenyl)thio]-, ethyl ester, (Z)-(125065-60-3)
• EPA Substance Registry System: Acetic acid, [(2-phenylethenyl)thio]-, ethyl ester, (Z)-(125065-60-3)

Safety Data

• Hazardous Substances Data: 125065-60-3(Hazardous Substances Data)

Upstream product

• 185844-35-3 (Z)-2-phenyl-1-trimethylsilylethenenethiol 
• 56583-94-9 (phenylacetyl)trimethylsilane 
• 536-74-3 phenylacetylene 
• 623-51-8 ethyl 2-sulfanylacetate 

Downstream Products

• 125065-58-9 2-[(E)-2-((Z)-2-Phenyl-ethenesulfonyl)-vinyl]-naphthalene 
• 125065-56-7 1-Ethoxy-4-[(E)-2-((Z)-2-phenyl-ethenesulfonyl)-vinyl]-benzene 
• 125065-57-8 1-Isopropyl-4-[(E)-2-((Z)-2-phenyl-ethenesulfonyl)-vinyl]-benzene 
• 125065-54-5 1-Fluoro-3-[(E)-2-((Z)-2-phenyl-ethenesulfonyl)-vinyl]-benzene 
• 125065-55-6 1-Bromo-4-[(E)-2-((Z)-2-phenyl-ethenesulfonyl)-vinyl]-benzene 
• 65350-61-0 bis(2-phenylvinyl)sulfone 
• 92207-24-4 (Z)-β-styrylsulfonylacetic acid 
• 1914-61-0 (Z)-Styrylthioacetic acid 

Relevant articles and documents

Chemistry of silyl thioketones. Part 10. Synthesis and reactivity of α-silyl vinyl sulfldes

Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.