125115-16-4

Basic information

• Product Name: Benzene, 1,1'-[5-hexenylidenebis(thio)]bis-
• CAS NO: 125115-16-4
• Molecular Formula: C18H20S2
• Molecular Weight: 300.489
• Mol File: 125115-16-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[5-hexenylidenebis(thio)]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[5-hexenylidenebis(thio)]bis-(125115-16-4)
• EPA Substance Registry System: Benzene, 1,1'-[5-hexenylidenebis(thio)]bis-(125115-16-4)

Safety Data

• Hazardous Substances Data: 125115-16-4(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 125115-14-2 1-chloro-1-phenylsulfanyl-5-hexene 
• 64818-36-6 5-hexenyl methanesulfonate 
• 108-98-5 thiophenol 
• 821-41-0 5-Hexen-1-ol 
• 39984-84-4 hex-5-en-1-yl(phenyl)sulfane 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 110434-51-0 trans-1-methyl-2-(phenylthio)cyclopentane 
• 110434-51-0 cis-1-methyl-2-(phenylthio)cyclopentane 
• 125115-14-2 1-chloro-1-phenylsulfanyl-5-hexene 
• 39984-84-4 hex-5-en-1-yl(phenyl)sulfane 

Relevant articles and documents

Generation and intramolecular cyclization of α-phenylsulfonyl and α-alkylsulfonyl radicals

α-Phenylsulfonyl radicals are generated by the reaction of diphenyl dithioacetals or phenyl α-chlorosulfides with tributyltin hydride. Alkyl phenyl dithioacetals react selectively with tributyltin hydride to give α-alkylsulfonyl radicals. 5-Exo-type of intramolecular cyclizations of these radicals are studied. The cyclization is most successful when the olefin is terminally substituted with an ester group. The cis/trans ratio of the cyclized product varies according to the reaction rates. With a faster cyclization, cis-isomer is the major product. A slower cyclization gives more trans-product.