125143-16-0Relevant articles and documents
REACTION OF 1-(4-TOLYL)THIOSEMICARBAZIDE WITH CHLOROACETONE. AN UNUSUAL CASE OF A BENZIDINE REARRANGEMENT
Rybinov, V. I.,Gorelik, M. V.,Tafeenko, V. A.,Medvedev, S. V.,Gurvich, V. Ya.
, p. 1127 - 1131 (2007/10/02)
The reaction of 1-(4-methylphenyl)thiosemicarbazide with chloroacetone leads to 4-methyl-2-thiazole, which undergoes a rearrangement of the benzidine type, being converted into 2-amino-4-methyl-5-(1-methyl-4-imino-2,5-cyclohex