1251901-57-1Relevant articles and documents
Influence of β-substituents in aldol reactions of boron enolates of β-alkoxy methylketones
Dias, Luiz C.,De Lucca Jr., Emilio C.,Ferreira, Marco A. B.,Garcia, Danilo C.,Tormena, Claudio F.
supporting information; experimental part, p. 5056 - 5059 (2011/02/26)
Moderate to good levels of substrate-based 1,5-syn-stereocontrol could be achieved in the boron-mediated aldol reactions of β-tert-butyl methylketones with achiral aldehydes, independent of the nature of the β-alkoxy protecting group (P = PMB or TBS). The