1252759-81-1Relevant articles and documents
Functionalized chiral ionic liquid catalyzed asymmetric SN1 α-alkylation of ketones and aldehydes
Zhang, Long,Cui, Lingyun,Li, Xin,Li, Jiuyuan,Luo, Sanzhong,Cheng, Jin-Pei
experimental part, p. 4876 - 4885 (2010/10/04)
Pyrrolidine-derived functionalized chiral ionic liquids (FCILs) have been found to catalyze asymmetric SN1 α-alkyl-ations of ketones and aldehydes with up to 99% yield, >99:1 dr and 87% ee. The FCIL catalysts enable SN1 α-alkylations