125331-46-6

Basic information

• Product Name: Ethyl N-Benzyl-N-<1-(3,4-dimethoxyphenyl)vinyl>urethane
• CAS NO: 125331-46-6
• Molecular Weight: 341.407
• Mol File: 125331-46-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethyl N-Benzyl-N-<1-(3,4-dimethoxyphenyl)vinyl>urethane(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl N-Benzyl-N-<1-(3,4-dimethoxyphenyl)vinyl>urethane(125331-46-6)
• EPA Substance Registry System: Ethyl N-Benzyl-N-<1-(3,4-dimethoxyphenyl)vinyl>urethane(125331-46-6)

Safety Data

• Hazardous Substances Data: 125331-46-6(Hazardous Substances Data)

Upstream product

• 1131-62-0 1-(3,4-dimethoxyphenyl)ethanone 
• 100-46-9 benzylamine 

Downstream Products

• 4732-70-1 3,4-dimethoxyphenylglyoxylic acid 
• 125331-47-7 4-acetoxy-3-benzyl-4-(3',4'-dimethoxyphenyl)oxazolidine-2,5-dione 

Relevant articles and documents

Oxidative Cyclization of Acyclic Aryl-Substituted N-Vinylurethanes

Oxidation of the acyclic N-(1-(1-naphthyl)vinyl)urethane (3) with lead tetraacetate (LTA) forms a naphthyloxazolone as the major product, accompanied by the product of rearrangement, N-(ethoxycarbonyl)-1-naphthylacetamide.When the naphthyl group is replaced by alkoxy-substituted aromatic rings, the N-vinylurethane undergoes three successive oxidations by LTA leading to novel substituted nitrogen containing cyclic anhydrides, oxazolidine-2,5-diones.The structure of this unusual oxidation product was proven by X-ray analysis.The mechanism of the oxidation is discussed in terms of known enamide oxidations, and the intermediacy of an oxazolone is demonstrated.