1253579-14-4

Basic information

• Product Name: 5-(5-bromo-picol-2-yl)-10,15,20-trimesitylporphinato-Zn(II)
• Synonyms: 5-(5-bromo-picol-2-yl)-10,15,20-trimesitylporphinato-Zn(II)
• CAS NO: 1253579-14-4
• Molecular Weight: 898.276
• Mol File: 1253579-14-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(5-bromo-picol-2-yl)-10,15,20-trimesitylporphinato-Zn(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(5-bromo-picol-2-yl)-10,15,20-trimesitylporphinato-Zn(II)(1253579-14-4)
• EPA Substance Registry System: 5-(5-bromo-picol-2-yl)-10,15,20-trimesitylporphinato-Zn(II)(1253579-14-4)

Safety Data

• Hazardous Substances Data: 1253579-14-4(Hazardous Substances Data)

Upstream product

• 31181-90-5 5-bromo-pyridine-2-carbaldehyde 
• 499219-41-9 5,10,15-trimesityl-20-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-porphyrinato-Zn(II) 
• 168823-76-5 5-bromo-2-(chloromethyl)pyridine 

Relevant articles and documents

Towards the synthesis of substituted porphyrins by a pyridyl group bearing a reactive functionality

Pyridyl-substituted porphyrins bearing a reactive functionality were prepared via Suzuki cross-coupling reactions and resulted in very good yields. These compounds are precursors of new porphyrin architectures able to coordinate two metals: one in the porphyrin core and the second around the pyridyl moiety. During the coupling reactions, a higher reactivity of a chloro picolyl group was evidenced compared to a bromo function on the same reacting molecule.