125416-31-1

Basic information

• Product Name: E-10-dicyclohexylsulfamoyl-D-isobornyl 4-hydroxy-5-phthalimidopent-2-enoate
• CAS NO: 125416-31-1
• Molecular Weight: 640.841
• Mol File: 125416-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: E-10-dicyclohexylsulfamoyl-D-isobornyl 4-hydroxy-5-phthalimidopent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: E-10-dicyclohexylsulfamoyl-D-isobornyl 4-hydroxy-5-phthalimidopent-2-enoate(125416-31-1)
• EPA Substance Registry System: E-10-dicyclohexylsulfamoyl-D-isobornyl 4-hydroxy-5-phthalimidopent-2-enoate(125416-31-1)

Safety Data

• Hazardous Substances Data: 125416-31-1(Hazardous Substances Data)

Upstream product

• 2436-29-5 3-(N-phthaloyl)propionaldehyde 
• 125416-26-4 10-dicyclohexylsulfamoyl-D-isobornyl (R)(+)-4-chlorophenylsulfinylacetate 
• 121703-15-9 10-dicyclohexylsulfamoyl-D-isobornyl chloroformate 
• 96303-88-7 (-)-10-dicyclohexylsulfamoyl-D-isoborneol 

Relevant articles and documents

Stereochemically matched sulfinylacetates for double diastereoselection in the spac reaction

4-Chlorophenylsulfinylacetates of defined stereochemistry at sulfur were prepared from monochiral alcohols: compound 2 from (+)-menthol; 3 and 4 from (-)-8-phenylmenthol; 5 and 6 from (+)-trans-2-phenylcyclohexanol; and, 7 and 9 from (-)-10-dicyclohexylsulfamoyl-D-isoborneol. Reagents for which the sulfoxide asymmetry is matched with the inducing effect of the auxiliary give good diastereoselection in SPAC reactions affording γ-hydroxy-α,β-unsaturatod alcohols of high optical purity. Asymmetry at the sulfoxide has a greater effect than the auxiliaries on the stereochemical outcome of these reactions.