1254470-73-9

Basic information

• Product Name: 2-methyl-1-(4-nitrophenylsulfonyl)-2-octylaziridine
• CAS NO: 1254470-73-9
• Molecular Weight: 354.47
• Mol File: 1254470-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methyl-1-(4-nitrophenylsulfonyl)-2-octylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-1-(4-nitrophenylsulfonyl)-2-octylaziridine(1254470-73-9)
• EPA Substance Registry System: 2-methyl-1-(4-nitrophenylsulfonyl)-2-octylaziridine(1254470-73-9)

Safety Data

• Hazardous Substances Data: 1254470-73-9(Hazardous Substances Data)

Upstream product

• 73901-01-6 p-nitrobenzenesulfonyl azide 
• 13151-27-4 2-methyl-dec-1-ene 

Relevant articles and documents

[FeIII(F20-tpp)Cl] Is an effective catalyst for nitrene transfer reactions and animation of saturated hydrocarbons with sulfonyl and aryl azides as nitrogen source under thermal and microwave-assisted conditions

[FeIII(F20-tpp)Cl] (F20tpp = meso- tetrakis(pentafluorophenyl)porphyrinato dianion) is an effective catalyst for imido/nitrene insertion reactions using sulfonyl and aryl azides as nitrogen source. Under thermal conditions, aziridination of aryl and alkyl alkenes (16 examples, 60-95% yields), sulfimidation of sulfides (11 examples, 76-96% yields), allylic amidation/amination of α-methylstyrenes (15 examples, 68-83% yields), and amination of saturated C-H bonds including that of cycloalkanes and adamantane (eight examples, 64-80% yields) can be accomplished by using 2 mol % [FeIII(F20- tpp)Cl] as catalyst. Under microwave irradiation conditions, the reaction time of aziridination (four examples), allylic amination (five examples), sulfimidation (two examples), and amination of saturated C-H bonds (three examples) can be reduced by up to 16fold (24-48 versus 1.5-6 h) without significantly affecting the product yield and substrate conversion.