1255524-58-3Relevant articles and documents
Rapid preparation of cycloheptane ring from 1,2-diketone and bis(iodozincio)methane via oxy-cope rearrangement using microflow system
Haraguchi, Ryosuke,Takada, Yoshiaki,Matsubara, Seijiro
, p. 628 - 629 (2012)
Treatment of 1,6-dialkylhexa-1,5-diene-3,4-diones with bis(iodozincio) methane at-78 °C for several hours gave cisdialkenylcyclopropane-1,2-diols which rearranged into the zinc alkoxides of cis-5,6-dialkylcyclohepta-3,7-diene- 1,3-diol in good yields at r
Preparation of a cycloheptane ring from a 1,2-diketone with high stereoselectivity
Takada, Yoshiaki,Nomura, Kenichi,Matsubara, Seijiro
supporting information; experimental part, p. 5204 - 5205 (2011/02/23)
Treatment of 1,6-dialkylhexa-1,5-diene-3,4-diones with bis(iodozincio) methane gave zinc alkoxides of cis-5,6-dialkylcyclohepta-3,7-diene-1,3-diol in good yields at room temperature. The reaction proceeded with high stereospecificity. Bis(iodozincio)metha