1256265-42-5Relevant articles and documents
Catalytic dicyanative [4 + 2] cycloaddition triggered by cyanopalladation using ene-enynes and cyclic enynes with methyl acrylate
Arai, Shigeru,Koike, Yuka,Hada, Hirohiko,Nishida, Atsushi
supporting information; experimental part, p. 7573 - 7579 (2011/02/25)
Palladium-catalyzed dicyanative [4 + 2] cycloaddition using various ene-enynes was investigated. The key species in this process is a cyanoallene intermediate that is obtained by the cyanopalladation of conjugated enynes followed by 5-exo-cyclization. To