1256556-19-0Relevant articles and documents
Near-Infrared Optogenetic Genome Engineering Based on Photon-Upconversion Hydrogels
Sasaki, Yoichi,Oshikawa, Mio,Bharmoria, Pankaj,Kouno, Hironori,Hayashi-Takagi, Akiko,Sato, Moritoshi,Ajioka, Itsuki,Yanai, Nobuhiro,Kimizuka, Nobuo
, p. 17827 - 17833 (2019)
Photon upconversion (UC) from near-infrared (NIR) light to visible light has enabled optogenetic manipulations in deep tissues. However, materials for NIR optogenetics have been limited to inorganic UC nanoparticles. Herein, NIR-light-triggered optogeneti
Perylene-derived triplet acceptors with optimized excited state energy levels for triplet-triplet annihilation assisted upconversion
Cui, Xiaoneng,Charaf-Eddin, Azzam,Wang, Junsi,Le Guennic, Boris,Zhao, Jianzhang,Jacquemin, Denis
, p. 2038 - 2048 (2014)
A series of perylene derivatives are prepared as triplet energy acceptors for triplet-triplet annihilation (TTA) assisted upconversion. The aim is to optimize the energy levels of the T1 and S1 states of the triplet acceptors, so that the prerequisite for TTA (2ET1 > E S1) can be better satisfied, and eventually to increase the upconversion efficiency. Tuning of the energy levels of the excited states of the triplet acceptors is realized either by attaching aryl groups to perylene (via single or triple carbon-carbon bonds), or by assembling a perylene-BODIPY dyad, in which the components present complementary S1 and T 1 state energy levels. The S1 state energy levels of the perylene derivatives are generally decreased compared to perylene. The anti-Stokes shift, TTA, and upconversion efficiencies of the new triplet acceptors are improved with respect to the perylene hallmark. For the perylene-BODIPY dyads, the fluorescence emission was substantially quenched in polar solvents. Moreover, we found that extension of the π-conjugation of BODIPY energy donor significantly reduces the energy level of the S1 state. Low S1 state energy level and high T1 state energy level are beneficial for triplet photosensitizers.
Metal-free reductive coupling of CO and CN bonds driven by visible light: Use of perylene as a simple photoredox catalyst
Okamoto, Shusuke,Kojiyama, Keita,Tsujioka, Hiroki,Sudo, Atsushi
supporting information, p. 11339 - 11342 (2016/09/23)
Perylene, a simple polycyclic aromatic hydrocarbon, was used as a photoredox catalyst to enable the reductive coupling reaction of aromatic aldehydes, ketones, and an imine under visible-light irradiation using a white LED.
