125669-25-2

Basic information

• Product Name: (C₆H₅)3BCN(CH₂)3OSi(CH₃)3
• CAS NO: 125669-25-2
• Molecular Weight: 399.416
• Mol File: 125669-25-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅)3BCN(CH₂)3OSi(CH₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)3BCN(CH₂)3OSi(CH₃)3(125669-25-2)
• EPA Substance Registry System: (C₆H₅)3BCN(CH₂)3OSi(CH₃)3(125669-25-2)

Safety Data

• Hazardous Substances Data: 125669-25-2(Hazardous Substances Data)

Upstream product

• 960-71-4 triphenylborane 
• 98748-92-6 3-trimethylsiloxy-1-phenylpropyl isocyanide 

Relevant articles and documents

Boron-Stabilized N,O-Carbenes. Triphenylboron Adducts of Siloxy- and Hydroxyalkyl Isocyanides and Spontaneous Formation of Ate-Ylids

Triphenylboron adducts of 2- and 3-hydroxyalkyl isocyanides spontaneously undergo intramolekular cyclization to give oxazolidin-2-ylidene and perhydrooxazin-2-ylidene boron complexes, respectively.The same compounds are obtained by methanolysis of the stable species Ph3B-CNCR1R2CR3R4-OSiMe3 (R1, R2, R3, R4 = H, alkyl) (2a - i) and Ph3B-CN(CH2)3-OSiMe3 (2j).IR, 1H NMR, 13C NMR, and mass spectra of the new compounds are reported. - Keywords: Functionalized Isocyanides; Borane Isocyanide Adducts; Reactions at Coordinated Ligands, N,O-Heterocyles, Carbene Complexes