1257792-97-4

Basic information

• Product Name: 2-methoxy-3-(trimethylsilyl)phenylboronic acid
• Synonyms: 2-methoxy-3-(trimethylsilyl)phenylboronic acid
• CAS NO: 1257792-97-4
• Molecular Weight: 224.14
• Mol File: 1257792-97-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methoxy-3-(trimethylsilyl)phenylboronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-3-(trimethylsilyl)phenylboronic acid(1257792-97-4)
• EPA Substance Registry System: 2-methoxy-3-(trimethylsilyl)phenylboronic acid(1257792-97-4)

Safety Data

• Hazardous Substances Data: 1257792-97-4(Hazardous Substances Data)

Upstream product

• 121-43-7 Trimethyl borate 
• 1152785-19-7 1-bromo-2-methoxy-3-(trimethylsilyl)benzene 
• 7732-18-5 water 

Downstream Products

• 1257793-14-8 3-iodo-2-methoxyphenylboronic acid 
• 1072951-59-7 3,5-diiodo-2-methoxyphenylboronic acid 

Relevant articles and documents

Electrophilic ipso-iodination of silylated arylboronic acids

Silylated functionalized arylboronic acids were converted into corresponding iodinated arylboronic acids in good yields via the electrophilic ipso-desilylation effected with iodine chloride in refluxing CHCl3. Disilylated arylboronic acids were susceptible to diiodination. In addition, the structural characterization and reactivity of a novel sterically hindered ortho-silylated diarylborinic ester were reported. The potential of selected iodinated phenylboronic acids as monomers for the Suzuki-Miyaura cross-coupling polymerization was demonstrated.