1258512-04-7

Basic information

• Product Name: (E)-2-(3-(4-chlorophenyl)-3-oxoprop-1-en-1-yl)benzaldehyde
• Synonyms: (E)-2-(3-(4-chlorophenyl)-3-oxoprop-1-en-1-yl)benzaldehyde
• CAS NO: 1258512-04-7
• Molecular Weight: 270.715
• Mol File: 1258512-04-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-2-(3-(4-chlorophenyl)-3-oxoprop-1-en-1-yl)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(3-(4-chlorophenyl)-3-oxoprop-1-en-1-yl)benzaldehyde(1258512-04-7)
• EPA Substance Registry System: (E)-2-(3-(4-chlorophenyl)-3-oxoprop-1-en-1-yl)benzaldehyde(1258512-04-7)

Safety Data

• Hazardous Substances Data: 1258512-04-7(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 34824-58-3 2-(2-bromophenyl)-1,3-dioxolan 
• 1777-56-6 4-chlorobenzoylmethylenetriphenylphosphorane 
• 103890-70-6 2-(diethoxymethyl)benzaldehyde 

Downstream Products

• 1258512-38-7 2'-(4-chlorobenzoyl)-1,2'-spirobi[indene]-1,3-dione 

Relevant articles and documents

Cobalt-Catalyzed Chemoselective Transfer Hydrogenative Cyclization Cascade of Enone-Tethered Aldehydes

The ligand-free Co-catalyzed chemoselective reductive cyclization cascade of enone-tethered aldehydes with i-PrOH as the environmentally benign hydrogen surrogate is developed by this study. Mechanistic studies disclosed that such a protocol is initiated

NHC-catalyzed spiro bis-indane formation via domino stetter - Aldol - Michael and stetter - Aldol - Aldol reactions

Two novel domino NHC-catalyzed spirocyclizations are described herein, enabling the rapid construction of three new carbon - carbon bonds and a quaternary center with high diastereoselectivity. A variety of spiro bis-indane structures are assembled in a single step from simple o-phthaldialdehyde derivatives.