125947-52-6Relevant articles and documents
TOTAL SYNTHESIS OF (+/-) ASPIDOFRACTININE
Dufour, Monique,Gramain, Jean-Claude,Husson, Henri-Philippe,Sinibaldi, Marie-Eve,Troin, Yves
, p. 3429 - 3432 (2007/10/02)
The pentacyclic skeleton 10 of the aspidospermine group of indole alkaloids has been constructed from hexahydrocarbazol-4-one 2 with high stereoselectivity.The synthesis of (+/-) 19-oxo aspidofractinine 12, a direct precursor of aspidofractinine 4, illustrates the usefulness of this new general strategy.