125996-98-7

Basic information

• Product Name: 4-Penten-1-one, 1-(3-methoxyphenyl)-
• CAS NO: 125996-98-7
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 125996-98-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 4-Penten-1-one, 1-(3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Penten-1-one, 1-(3-methoxyphenyl)-(125996-98-7)
• EPA Substance Registry System: 4-Penten-1-one, 1-(3-methoxyphenyl)-(125996-98-7)

Safety Data

• Hazardous Substances Data: 125996-98-7(Hazardous Substances Data)

Upstream product

• 27834-99-7 ethyl (3-methoxybenzoyl)acetate 
• 586-37-8 1-(3-Methoxyphenyl)ethanone 
• 7103-09-5 4-but-1-enylmagnesium bromide 
• 1711-05-3 m-anisoyl chloride 
• 591-31-1 3-methoxy-benzaldehyde 
• 107-18-6 allyl alcohol 
• 5000-65-7 2-bromo-3'-methoxyacetophenone 
• 217805-03-3 tris-4,4,5,5,6,6,7,7,7-nonafluoroheptyl allyl stannane 
• 125997-10-6 1-(3-Methoxy-phenyl)-pent-4-en-1-ol 
• 82772-51-8 2-chloro-3'-methoxyacetophenone 

Downstream Products

• 1170699-87-2 (E)-4-methoxy-N-[1-(3-methoxyphenyl)pent-4-en-1-ylidene]aniline 
• 125997-02-6 C₁₃H₁₄⁽²⁾H₂O 

Relevant articles and documents

Selective α-monoallylation of phenyl ketones and benzocycloalkanones under microwave irradiation

A method for the selective α-monoallylation of phenyl ketones and benzocycloalkanones with allyl alcohol under microwave irradation is described. The corresponding α-allyl ketones are obtained in moderate to good yields with only minor quantities of diallylation by-products.

Radical Aza-Cyclization of α-Imino-oxy Acids for Synthesis of Alkene-Containing N-Heterocycles via Dual Cobaloxime and Photoredox Catalysis

Nitrogen-containing heterocycles are prevalent in both naturally and synthetically bioactive molecules. We report herein an unprecedented protocol for radical aza-cyclization of α-imino-oxy acids with pendant alkenes via synergistic photoredox and cobaloxime catalysis. With or without alkenes as the intermolecular cross-coupling partners, the transformation provides a variety of corresponding alkene-containing dihydropyrrole products in satisfactory yields. In the presence of external alkenes, the tandem reaction generates E-selective coupling products with excellent chemo- and stereoselectivity.

'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions

A new generation of propylene-spaced fluorous allyltin reagents [(Rf(CH2)3)3SnCH2CH=CH2] is described. These succeed in radical allylations where their lower homologs (ethylene-spaced) fail, and they provide improved performance in transition metal catalyzed allylations. The reagents and byproducts are readily separated by simple fluorous-organic liquid-liquid or solid-liquid extractions.