125997-05-9Relevant articles and documents
Mechanism of the palladium dichloride catalyzed cope rearrangement of acyclic dienes. A substituent effect study
Overman, Larry E.,Renaldo, Alfred F.
, p. 3945 - 3949 (2007/10/02)
The PdCl2-catalyzed Cope rearrangement of eight 2-aryl-1,5-hexadienes was studied. No simple substituent effect relationship was found, since the catalyzed-rearrangement rate was decreased by introducing both electron-withdrawing and electron-d