1259987-95-5

Basic information

• Product Name: MorDalPhos AuCl
• Synonyms: Chloro{4-[2-bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]phenylmorpholine}gold(I);Chloro{4-[2-di(1-adamantyl)phosphino]phenylmorpholine}gold(I);MorDalPhos AuCl
• CAS NO: 1259987-95-5
• Molecular Formula: C₃₀H₄₂AuClNOP
• Molecular Weight: 697.07
• Mol File: 1259987-95-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: MorDalPhos AuCl(CAS DataBase Reference)
• NIST Chemistry Reference: MorDalPhos AuCl(1259987-95-5)
• EPA Substance Registry System: MorDalPhos AuCl(1259987-95-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• Hazardous Substances Data: 1259987-95-5(Hazardous Substances Data)

Upstream product

• 29892-37-3 chloro(dimethylsulfide) gold(I) 
• 1237588-12-3 N-(2-(di(1-adamantyl)phosphino)phenyl)morpholine 

Downstream Products

• 1616297-82-5 Mor-DaIPhos-Au(phthalimide) 
• 1259988-00-5 Au(P(C₁₀H₁₅)2C₆H₄NC₄H₈O)(NHC₄H₈O)⁽¹⁺⁾*B(C₆F₅)4^(1-)=Au(P(C₁₀H₁₅)2C₆H₄NC₄H₈O)(NHC₄H₈O)B(C₆F₅)4 
• 1259987-98-8 Au(P(C₁₀H₁₅)2C₆H₄NC₄H₈O)(C₆H₁₀)⁽¹⁺⁾*B(C₆F₅)4^(1-)=Au(P(C₁₀H₁₅)2C₆H₄NC₄H₈O)(C₆H₁₀)B(C₆F₅)4 

Relevant articles and documents

One-step synthesis of methanesulfonyloxymethyl ketones via gold-catalyzed oxidation of terminal alkynes: A combination of ligand and counter anion enables high efficiency and a one-pot synthesis of 2,4-disubstituted thiazoles

By using Mor-DalPhos as the P,N-bidentate ligand and mesylate as the counter ion, the resulting gold(I) complex catalyzes efficient oxidative transformations of various terminal alkynes into synthetically versatile methanesulfonyloxymethyl ketones. The mild reaction conditions and high efficiency permit the one-pot synthesis of a range of valuable 2,4-disubstituted thiazoles by subjecting the resulting reaction mixture to a further condensation with thioamides under mild conditions.