1260104-28-6

Basic information

• Product Name: trans-ethyl N-{2-[2-phenylethenyl]phenyl}aminoacetate
• Synonyms: trans-ethyl N-{2-[2-phenylethenyl]phenyl}aminoacetate
• CAS NO: 1260104-28-6
• Molecular Weight: 281.354
• Mol File: 1260104-28-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-ethyl N-{2-[2-phenylethenyl]phenyl}aminoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: trans-ethyl N-{2-[2-phenylethenyl]phenyl}aminoacetate(1260104-28-6)
• EPA Substance Registry System: trans-ethyl N-{2-[2-phenylethenyl]phenyl}aminoacetate(1260104-28-6)

Safety Data

• Hazardous Substances Data: 1260104-28-6(Hazardous Substances Data)

Upstream product

• 27652-35-3 (E)-2-styrylaniline 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 1260104-32-2 trans-N-{2-[2-phenylethenyl]phenyl}aminoacetic acid 

Relevant articles and documents

Synthesis and photochemistry of 3-(o-stilbeneyl)-4-H/Me/Ph-sydnones; Intramolecular cyclization to 1,2-benzodiazepines and/or quinolines

Stilbeneylsydnone derivatives were synthesized by a sequence of reactions in good yields. Irradiation of 3-stilbeneyl-4-methylsydnone 4 gives 1H-1,2-benzodiazepine derivative 7 as the main product along with 2-methylquinoline derivative 20. Irradiation of 3-stilbeneyl-4-phenylsydnone 5 afforded only 1H-1,2-benzodiazepine derivative 8 whereas on irradiation of 4-unsubstituted 3-stilbeneylsydnone 3 no benzodiazepine derivative was detected. An efficient novel photochemical approach to 1H-1,2-benzodiazepines has been found from the new 3-(o-stilbeneyl)-4-substituted-sydnones via intramolecular 1,7-electrocyclization reaction of the photogenerated nitrile imines.