1260503-82-9

Basic information

• Product Name: (S)-tetrahydro-3,3-diphenyl-1-(2,4,6-trifluorophenyl)-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
• Synonyms: (S)-tetrahydro-3,3-diphenyl-1-(2,4,6-trifluorophenyl)-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
• CAS NO: 1260503-82-9
• Molecular Weight: 393.216
• Mol File: 1260503-82-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-tetrahydro-3,3-diphenyl-1-(2,4,6-trifluorophenyl)-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-tetrahydro-3,3-diphenyl-1-(2,4,6-trifluorophenyl)-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole(1260503-82-9)
• EPA Substance Registry System: (S)-tetrahydro-3,3-diphenyl-1-(2,4,6-trifluorophenyl)-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole(1260503-82-9)

Safety Data

• Hazardous Substances Data: 1260503-82-9(Hazardous Substances Data)

Upstream product

• 22348-32-9 (S)-diphenylprolinol 
• 182482-25-3 2,4,6-trifluorophenylboronic acid 

Relevant articles and documents

Rational electronic tuning of CBS catalyst for highly enantioselective borane reduction of trifluoroacetophenone

α,α,α-Trifluoroacetophenone (2), which is susceptible to noncatalytic reduction by BH3, could be reduced to chiral alcohol up to 90% ee by using electronically tuned-CBS catalyst (1) with BH3. The enantioselectivities highly correlated with the differential orbital energies between 1-BH3 adduct and 2, which were calculated by DFT method.