1260900-88-6

Basic information

• Product Name: C₁₅H₂₁BN₄O₂S
• Synonyms: C₁₅H₂₁BN₄O₂S
• CAS NO: 1260900-88-6
• Molecular Weight: 332.234
• Mol File: 1260900-88-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₁BN₄O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₁BN₄O₂S(1260900-88-6)
• EPA Substance Registry System: C₁₅H₂₁BN₄O₂S(1260900-88-6)

Safety Data

• Hazardous Substances Data: 1260900-88-6(Hazardous Substances Data)

Upstream product

• 13183-79-4 1-methyl-5-mercaptotetrazole 
• 214360-74-4 2-(3-(bromomethyl)phenyl)-4,4,5,5,-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Microwave-mediated synthesis of an arylboronate library

A series of arylboronates has been synthesized from the reaction of 2-(2-, (3-, or (4-(bromomethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1{1-3} respectively with a range of N-, S-, and O-nucleophiles, using microwave-mediated chemistry. For the synthesis of N- and S-substituted boronates, a supported base, PS-NMM, was employed, and many reactions were complete within 15 min. With O-nucleophiles, a mixture of tetrabutylammonium bromide, potassium carbonate, and sodium hydroxide was employed. The resulting aminomethyl, mercaptomethyl, or alkoxy-/phenoxymethyl-arylboronates were subjected to microwave-mediated Suzuki Miyaura coupling reactions to afford a range of biaryls in moderate to good yields. The X-ray structures of five boronates were determined.