126181-81-5Relevant articles and documents
Visible-Light-Mediated Regioselective Allylation, Benzylation, and Silylation of Methylene-Malononitriles via Photoredox-Induced Radical Cation Fragmentation
Liu, Rongfang,Chia, Shane Pui Mun,Goh, Yi Yiing,Cheo, Han Wen,Fan, Binbin,Li, Ruifeng,Zhou, Rong,Wu, Jie
, p. 1459 - 1465 (2019/08/21)
Visible-light-mediated regioselective allylation, benzylation, and silylation of methylene-malononitriles using allylic/benzylic silane and disilane reagents have been developed, delivering the corresponding allylated, benzylated, and silylated products i
PHOTOSILYLATION OF ELECTRON-DEFICIENT ALKENES BY USE OF DISILANES VIA PHOTOINDUCED ELECTRON-TRANSFER
Mizuno, Kazuhiko,Nakanishi, Kazuhisa,Chosa, Jun-ichi,Nguyen, Tien,Otsuji, Yoshio
, p. 3689 - 3692 (2007/10/02)
The photosilylation on electron-deficient alkenes such as 1-aryl-2,2-dicyanoethenes occurred regioselectively at the β-position to the electron-withdrawing groups upon irradiation with disilanes and trisilane.