126253-84-7

Basic information

• Product Name: (3(2R),4S)-3-<2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-1-oxo-3-phenylpropyl>-4-(phenylmethyl)-2-oxazolidinone
• Synonyms: (3(2R),4S)-3-<2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-1-oxo-3-phenylpropyl>-4-(phenylmethyl)-2-oxazolidinone
• CAS NO: 126253-84-7
• Molecular Weight: 540.539
• Mol File: 126253-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3(2R),4S)-3-<2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-1-oxo-3-phenylpropyl>-4-(phenylmethyl)-2-oxazolidinone(CAS DataBase Reference)
• NIST Chemistry Reference: (3(2R),4S)-3-<2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-1-oxo-3-phenylpropyl>-4-(phenylmethyl)-2-oxazolidinone(126253-84-7)
• EPA Substance Registry System: (3(2R),4S)-3-<2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-1-oxo-3-phenylpropyl>-4-(phenylmethyl)-2-oxazolidinone(126253-84-7)

Safety Data

• Hazardous Substances Data: 126253-84-7(Hazardous Substances Data)

Upstream product

• 39637-99-5 (S)-(+)-2-methoxy-2-trifluoromethyl-2-phenylacetyl chloride 

Downstream Products

• 126191-13-7 (R)-3-phenyl-2-((R)-3,3,3-trifluoro-2-methoxy-2-phenylpropionylamino)propionic acid 
• 126191-15-9 benzyl 2(R)-2-<<(+)-2-methoxy-2-(trifluoromethyl)-2-phenylacetyl>amino>-3-phenylpropionate 

Relevant articles and documents

ASYMMETRIC HALOGENATION OF CHIRAL IMIDE ENOLATES. A GENERAL APPROACH TO THE SYNTHESIS OF ENANTIOMERICALLY PURE α-AMINO ACIDS.

The chiral N-acyl oxazolidones 2, as the derived dibutyl boron enolates, have been demonstrated to undergo diastereoselective bromination and subsequent azide displacement to give the α-azido carboximides 4a (5 cases).These adducts may be hydrolyzed under mild conditions to the enantiomerically pure α-azido carboxylic acids 5a.