126314-04-3

Basic information

• Product Name: methyl 2-benzoyl-2-cyclopropylpropionate
• Synonyms: methyl 2-benzoyl-2-cyclopropylpropionate
• CAS NO: 126314-04-3
• Molecular Weight: 232.279
• Mol File: 126314-04-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-benzoyl-2-cyclopropylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-benzoyl-2-cyclopropylpropionate(126314-04-3)
• EPA Substance Registry System: methyl 2-benzoyl-2-cyclopropylpropionate(126314-04-3)

Safety Data

• Hazardous Substances Data: 126314-04-3(Hazardous Substances Data)

Upstream product

• 126314-03-2 methyl 2-benzoyl-2-cyclopropyl-3-iodopropionate 
• 126314-00-9 methyl 2-cylopropyl-3-oxo-3-phenylpropanoate 
• 74-88-4 methyl iodide 
• 34108-21-9 methyl cyclopropylacetate 
• 126314-01-0 methyl 2-cylopropyl-3-hydroxy-3-phenylpropanoate 
• 100-52-7 benzaldehyde 

Relevant articles and documents

REACTIONS RELATED TO COENZYME B12 DEPENDENT REARRANGEMENTS: METAL MEDIATED FREE RADICAL ACYL MIGRATIONS IN METHYL AND CYCLOPROPYL SUBSTITUTED MODELS

Free radicals generated from the methylmalonylcoenzyme A mutase model substrates (3) and (4) by chromium(II) reduction, or by pyrolysis of the analogous cobaloximes, underwent -migration only in the acyl series (R=Ph, Me) and not the critical ester series (R=OEt, SBu).The mechanism of the migration was implied by incorporation into (4) of the cyclopropyl ring, the opening of which demonstrated the free radical nature of rearranged intermediate.