126330-71-0Relevant articles and documents
1,2-cis-β-Mannopyranoside Formation by the Dimethylphosphinothioate Method
Yamanoi, Takashi,Nakamura, Kazumi,Takeyama, Hiroshi,Yanagihara, Kenji,Inazu, Toshiyuki
, p. 343 - 346 (1993)
1,2-cis-β-Mannopyranosides were obtained predominantly by reactions of mannopyranosyl dimethylphosphinothioate derivatives with several alcohols in the presence of iodine and a catalytic amount of triphenylmethyl perchlorate as the activator in benzene.
Stereoselective synthesis of β-rhamnopyranosides via gold(i)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors
Zhu, Yugen,Shen, Zhengnan,Li, Wei,Yu, Biao
supporting information, p. 1536 - 1539 (2016/02/09)
Stereoselective β-rhamnopyranosylation remains a challenge, due to the unfavorable anomeric effect and steric hindrance of the C2-substituent; herein, this challenge is addressed with a gold(I)-catalyzed SN2-like glycosylation protocol employin
New Synthetic Methods and Reagents for Complex Carbohydrates. VIII. Steroselective α- and β-Mannopyranoside Formation from Glycosyl Dimethylphosphinothioates with the C-2 Axial Benzyloxyl Group
Yamanoi, Takashi,Nakamura, Kazumi,Takeyama, Hiroshi,Yanagihara, Kenji,Inazu, Toshiyuki
, p. 1359 - 1366 (2007/10/02)
The reactions of mannopyranosyl dimethylphosphinothioates and alcohols using silver perchlorate as an activator in the presence of molecular sieves 4A in benzene at room temperature gave the 1,2-trans-α-mynnopyranosides in good yields.On the other hand, 1